Research Activities top

Laboratory of molten salts (Dr. N. Ene) is specialized in obtaining physico-chemical data (phase diagrams, density, viscosity, electrical conductivity), in order to characterize various molten salts systems and to elucidate the mechanisms of processes involved in their practical applications. The basic and applied problems related to electrochemistry of light and refractory metals and electrosynthesis of special materials are studied. The environmental protection concerning waste inertization and recycling of valuable materials is now in progress.Heat storage and heat transfer in molten salts related to their utilization in non-conventional energy sources are also investigated. Studies devoted to biocompatible vitroceram -metal systems for implantology applications are now in progress too.
The activity of the Molten State Laboratory is developed in the frame of the "Physical Chemistry of Molten Salts and electrochemical fundamentals of industrial processes involving the molten salts use".

The program is divided in two projects:

1. Electrochemistry in molten salt systems, devoted to fundamental studies of some electrochemical processes in molten salts.
* Investigation of the redox chemistry and electrodeposition of metals with high affinity for oxygen and water, such titanium, hafnium, molybdenum and tungsten, in different alkali halide melts, such LiCl - KCl, NaF - LiF - KF, by linear and cyclic voltammetry and stationary techniques;
* Investigation of the complex chemistry of refractory metals and boron in general and especially the effect of fluoride ion and the atomic ratio Me/B and F/Cl/O in electrosynthesis of refractory boride;
* Fundamental and applied study in used voltammetry in molten salt electrochemistry; simulation of the electrochemical process and correlation between the experimental data and the physico - chemical models;
* Study of the electrocrystallization process associated with electrodeposition of refractory metals and refractory boride;
* Fundamental and applied study in electrometallurgy and electro-deposition of some earth metal (Ce, Nd, Dy) in molten electrolyte;
* Study of inert anode (based on oxides) in electrodeposition of aluminum; electrode process, kinetics and current efficiency.

2. The molten salts structure and their physico-chemical properties, devoted to studies in:
* Physical chemistry of molten salts:
* electrical conductivity, chemical and mechanical stability characterization of molten salts and oxidic materials,
* structural investigations using IR and Raman spectroscopy, NMR, X ray diffraction in molten salts and vitreous oxides,
* phase diagrams,
* Environmental protection
* Heat storage of solar and residual industrial energy in phase change materials.
* Seasonal chemical storage in methanol using absorption of CO2 from the atmosphere in hollow fibers, oxidative degradation of organic wastes in molten carbonates.
* Vitrification of industrial wastes and physico-chemical characterization of materials obtained.

Chemical stability tests for the obtained glasses and electrical conductivity measurements in molten state as tools for evaluating their quality.
* Modeling of electrical conductivity in molten salts and multicomponent oxidic glasses.
* Correlation between composition-structure-thermal history of glasses, mainly containing heavy metals.
* Crystallization tendency evaluated by DTA measurements and a mathematical model concerning the crystallization kinetics is in progress.
* Biocompatible vitroceramic-metal systems for implantology applications:
* Characterization of the obtained systems.
* Interface phenomena and diffusion processes in the solid state.
* Hardening of metallic surfaces by diffusion processes with and without reaction.


Research Team top



Dr. Nicolae Ene, senior researcher 1, Head of Laboratory nene@icf.ro
Dr. Mircea Corneliu Olteanu, senior researcher 1, Scientific Secretary; oltenu_001@yahoo.com
Dr. Mariella Constantinescu, senior researcher1 ellaconstantinescu@k.ro
Dr. Mirela Britchi, senior researcher 1; iuliab40@yahoo.com
Dr. Ion Galasiu, senior researcher1;
Dr. Maria Elena Anghel, senior researcher3; manghel@icf.ro
Dr. Ana Maria Popescu, senior researcher 3; ampop@icf.ro
Dr. Petrica Mircea Pavel, senior researcher3; pavel@icf.ro
Dr. Constantin Virgil, senior researcher;vconstan@icf.ro
Cristina Donat, researcher, PhD student; cdonath@icf.ro
Rozalia Piper, researcher, PhD student;
Alina Solomon, research assistant , Master student
Elena Ciurla, research assistant, PhD Student
Elena Stroe, research assistant, PhD student
Technical laboratory team:
Maria Pilescu
Elena Pataliu
Elena Ene

International Projects and Scientific Collaborations top


1. CRMHT-CNRS-Romanian Academy cooperation:
"Etude du systeme NaCl-Na2B4O7-Na3AlF6-TiO2 par RMN haute resolution solide et haute temperature"
at Centre de Recherche sur les Materiaux a Haute Temperatures-CNRS, Orleans, France, 2000-2003.
( C.Bessada-M.Olteanu)

2. CNRS-Romanian Academy cooperation:
"Etude du systeme NaCl-Na2B4O7-Na3AlF6-TiO2 par RMN haute resolution solide et haute temperature"
at Centre de Recherche sur les Materiaux a Haute Temperatures- CNRS, Orleans, France 2003-2005
(C. Bessada-E.M.Anghel)

3. CNRS-Romanian Academy cooperation:
"Structure-property correlation in some glass-ceramics obtained by industrial waste vitrification"
at Centre de Recherche sur les Materiaux a Haute Temperatures-CNRS, Orleans, France, 2001-2003
(P. Echegut-M. Constantinescu)

4. Professeur invite a Universite d'Orleans-ESEM, M.Constantinescu.
Cours-conferences ( 5 06 -5 08 2001 et 1 -31 10 2002)

5 CNRS-Romanian Academy cooperation:
"Structure-property correlation in some glass-ceramics obtained by industrial waste vitrification"
at Centre de Recherche sur les Materiaux a Haute Temperatures-CNRS, Orleans, France, 2003-2005
(M.Malki-M.Constantinescu)

Grants:
1. MCT 1998-1999,
"Residue inertization by vitrification. Physico-chemical properties of some oxidic glasses in solid and in molten state".
Resp. M.Olteanu

1'. MCT 1998-1999
Phenomenons and mechanisms at the interface vitroceramic coating- metallic substrate.
Resp. M. Britchi

2. ANSTI, 1999-2001
"Physico-chemical characterization of vitroceramic-metal systems with application in implantology"
Resp. M. Britchi

3. Romanian Academy:
"Influence of heavy metals on structure and properties of vitroceramics obtained from industrial waste",
Contract no. 293, 2000. Resp: Mircea Olteanu

4. ANSTI,2000-2001
"Structure and phase equilibria of the ternary subsystems in NaCl-Na2B4O7-Na3AlF6-TiO2"
Contract no. 6124, Resp. E.M.Anghel

5. Romanian Academy:
"Physico-chemical substantiation of the oxidic glasses obtaining from secondary waste of battery plants and their characterization."
Contract no.41, 38, 2003-200$ Resp. GAR Mircea Olteanu.

Prizes
1. Prize "Nicolae Teclu" of the Romanian Academy, 1993 for:
"Electrochemistry and electrometallurgy of titanium in molten electrolytes",
dr. Ene Niculae

2. Prize "I. G. Murgulescu" of the Romanian Academy, 1994 for:
"Physico-chemical characterization of some systems used in light metal electrometallurgy",
dr. Mircea Corneliu Olteanu

3. Prize "Gheorghe Spacu" of the Romanian Academy, 1999 for :
"Physico-chemical fundamentals of new procedures or recycling industrial wastes and residual energies"
dr. Mariella Constantinescu

Publications top

top
1. M.Constantinescu ,R.Piper, M.Olteanu, M.Malki, C.Bessada, P.Echegut
"Chemical stability of glasses with compositions similar to the non-volatile fraction of industrial wastes".
Glass Technology, 2005, in press.

2. M. Malki, M. Constantinescu, P. Echegut, C. Bessada, E. M. Anghel, R. Piper, M. Olteanu
"Structure and properties of glasses obtained by recycling secondary lead from acid battery plants"
Glass Technology, 2005, 46, xxx-xxx.

3. M. Britchi, M. Olteanu, N. Ene
"Optical microscopy and microhardness characterization of some biovitoceramics used as coatings on titanium"
Int. J. of Materials and Product Technology, 2005, 25, xxx-xxx.

4. N. Ene and Cristina Donath
Electrochemical behaviour of some niobium compounds in molten (KCl-NaF-LiF)eut electrolytes.
Revue Roumaine de Chimie 2004, 49(2), pp. 105-111.

4. 5. C. Bessada, E. M. Anghel
"11B, 23Na, and 27Al NMR study of solid and molten Na3AlF6-Na2B4O7",
Inorg. Chem. 42[12] (2003) 3884-3890.

6. P. M. Pavel, M. Constantinescu, N.Ene
"Planar solidification with mushy zone of a binary molten salt mixture"
Proceedings of the "Futurestock Conference2003 ",Poland, pp. 59-65

7. V. Constantin, A. M. Popescu, S. Zuca, M. Gaune-Escard, M. Olteanu
The cathodic behviour of a cerium compound in fluoro-chloro melt
Ann. West Univ. Timisoara, 2003, 12, 513-518.

8. M. Britchi, M. Olteanu, N. Ene, B. Grigoras, C. Mazilu
Evolution of fracture toughness and britleness from Vickers hardness measurements on biovitroceramic coatings
Ann. West Univ. Timisoara, 2003, 12, 997-1006.

9. T.R. Griffiths, V.A. Volkovich and E.M. Anghel,
" Molten Salt Oxidation: A Reassessment of its supposed catalytic mechanism and hence its development for the disposal of waste automotive tires",
Proceeding of The Thirteenth International Symposium of Molten Salts, eds. H.C. Delong, R.W. Bradshaw,
M. Matsunaga, G.R. Stafford and P.C. Trulove, The Electrochem. Soc., Pennington, NJ, 2002, pp. 306-317.

10. N. Ene and Cristina Donath,
"Electrochemical investigation of dissolved K3MoCl6 in molten alkali halide electrolytes"
Revue Roumaine de Chimie, 2003, 48/10, 761-768

11. N. Ene, Cristina Donath
"Electrochemistry of K3MoCl6 in molten electrolytes"
Annals of West University of Timisoara, Series Chemistry, 12(3) 2003, p. 519-526

12. Cristina Nicolescu, Rodica Galasiu, I. Galasiu, G. Vlaicu, G. H. Haarberg, J. Thonstad
"Studiul influentei continutului de alumina asupra distributiei impuritatilor cu continut de vanadiu in amestecuri criolit alumina".
Revista de Chimie 54, nr. 6. 2003, p. 512-515.

13. Cristina Nicolescu, Rodica Galasiu, I. Galasiu, G. Vlaicu, G. H. Haarberg, J. Thonstad
"Studiul influentei continutului de alumina asupra distributiei impuritatilor cu fier in amestecuri criolit Alumina"
Revista de Chimie 54, nr. 6. 2003, p. 372-374

14. V. Constantin, Ana Maria Popescu, Stefania Zuca
" Preliminary studies of the obtainin of solid metallic cerium from fluoride melts"
Z. Naturforsch., 58 a, pp. 57-62, 2003

15. M Malki, M. Constantinescu, I. Nuta, P. Echegut and M. Olteanu
"Electrical conductivity of glasses containing PbO in solid and molten state"
Proceedings of the "10-th International Ceramics Congress and 3rd Forum of New Materials CIMTEC, Florence, July 2002", SII-1E:P17

16. M. Malki., C. Bessada, P. Echegut, M. Constantinescu, O. Mocioiu and M. Olteanu,
"Evolution of transport properties with temperature and composition in waste glasses".
Proceedings of the 16-th European Conference for Thermophysical Properties ECTP, 2002,.

17. M. Britchi, M. Olteanu, G. Jitianu, D. Crisan, O. Mocioiu
"Mechanical behaviour of some glass-ceramics used as coatings on biocompatible materials"
Proceed. of The 2nd Conf. "New Research Trends in Material Science", Constanta, Romania, 2002, pp. 266-270 .

18. M. Britchi, M. Olteanu, G. Jitianu, D. Gheorghe, M. Branzei
"Composite biovitroceramic materials as coating layers on biocompatible metallic supports"
Acta Techn. Napocensis, 2002, 45, 149-154.

19. M. Britchi, M. Olteanu, D. Gheorghe, M. Brハzei
"Hardening of metallic surfaces by processes implying diffusion (with and without reactions)"
Surface Modification Technologies XV, Eds. T. S. Sudarsan, J. J. Stigchlich, M. Jeandin, ASM International, Materials Park, Ohio and IOM Communications Ltd., UK, 2002, pp. 287-297.

20. M. Britchi, G. Jitianu, M. Olteanu, D. Crisan, A. Marcu, P. Nita
"Vitroceramic oxidic systems as coating layers on pure titanium (biomedical substrates)"
Surface Modification Technologies XV, Eds. T. S. Sudarsan, J. J. Stiglich, M. Jeandin, ASM International, Materials Park, Ohio and IOM Communications, UK, 2002, pp. 299-306.

22. M. Britchi, M. Olteanu, M. Brハzei, D. Gheorghe
"Hardening of copper surfaces by beryllium diffusion"
Int. J. of Materials and Product Technology, 2002, 17, 659-671.

23. E.M. Anghel, M. Balasoiu, S. Zuca, E.Segal,
"Phase equillibria in the NaCl-Na3AlF6-Na2B4O7-TiO2 system",
High temp.-High Pres. 33 ,2001, 411-417.

24. L. Nicolescu, Rodica Galasiu, I. Galasiu
"Influence of frequency of anode effect duration on the vanadium concentration in the aluminum obtained by electrolysis in cryolite-alumina melts"
Procc. of the 12th Romanian International Conference on Chemistry and Chemical Engineering, 2001, sept. 13-15, Bucharest, pp. 294-298

25. M.F. Rolea, I. Galasiu, Rodica Galasiu
"Physical and electrochemical characteristics of the ceramic semiconductors based on SnO2"
Procc. of the 12th Romanian International Conference on Chemistry and Chemical Engineering, 2001, sept. 13-15, Bucharest, pp. 156-161

26. C. Nicolescu, Rodica Galasiu, I. Galasiu, J. Thonstad, G.M. Haarberg
"Study of interactions between carbon dust and some impurities (Fe and V) of electrolyte used at aluminum Electrolysis"
Procc. 2ndInternational Symposium on Electrochemistry- A Frontier field of Theoretical and Practical Interest, 2001, sept. 13-15, Bucharest, 342-348

27. Cristina Donath, N. Ene
"Electroreduction of Nb ions in the molten alkali halide"
Second European Conference and Exhibition on Advanced Materials and Technology, 2001, 9-13 sept. Bucharest, pp. 61-68

28. Cristina Donath, N. Ene
"Studies of Niobium electrtochemistry in KCl-NaF-LiF molten electrolytes"
Procc. 2nd International Symposium on Electrochemistry- A Frontier Field of Theoretical and Practical Interest, 2001, sept. 13-15, Bucharest, CD-09

29. Cristina Donath, N. Ene
"Contribution to chemistry and electrochemistry of Nb ions in molten electrolytes"
The 2nd National Conference "New Research trends in Material Science" 2001, Constanta 24- 26 sept. pp. 67-69

30. Suzana Mihaiu, Gh. Aldica, Ana Maria Popescu, O. Scarlat, Maria Zaharescu
"SnO2-based ceramics with electronic type conduction"
Conferinta Jubiliara a Societatii de Ceramica, 2001, 22 iunie, Bucuresti, pp. 61-62

31. Maria Ileana Ionita, N. Ene and M. Vanatoru,
"Sonoelectrochemical studies of the ethanol oxidation in alkali medium"
Revue Roumaine de Chimie, 2001, 46/6, 637-647

32. Mariana Marin, Mioarea stroe and N. Ene
"Electrochemistry and electrodeposition of some refractory metals in molten salts"
Revue Roumaine de Chimie, 2001, 46/5, 463-480

33. T. Griffiths, S. Barr, V.A.Volkovich, E.M. Anghel,
"Destruction of organic wastes using molten carbonate",
Proceeding of the 6th International Symposium on the Molten Salts Chemistry and Technology,eds. C.Nianyl and Q. Zhiyu., Shanghai University Press, 2001, pp 130-135.

34. C. Bessada, E.M. Anghel,
" Nuclear Magnetic Resonance studies of the Na2B4O7-Na3AlF6 system",
Proceeding of the 6th International Symposium on the Molten Salts Chemistry and Technology, eds. C.Nianyl and Q. Zhiyu, Shanghai University Press, 2001, pp 65-68.

35. C. Bessada, M. Constantinescu, E.M. Anghel, M. Malki, P. Echegut, M. Olteanu,
"Influence of PbO content on the properties of some oxide glasses that reproduce industrial wastes",
Proceeding of the 6th International Symposium on the Molten Salts Chemistry and Technology, Eds. C.Nianyl and Q. Zhiyu., Shanghai University Press, 2001, pp 61-64.

36. I. Pencea, V. Manoliu, I. Vasiliu, M. Britchi, M. Olteanu
"SEM, EDS and WAXD microstructural characterization of a new enamel used as protective and thermal barrier"
J. Material and Product Technology, 2001, 16, 658 - 668.

37. M. Britchi, M. Olteanu, G. Jitianu, M.Brハzei, D. Gheorghe, P. Nita
"Preparation and characterization of biocompatible vitroceramic-metal systems for applications in medicine"
Surface Engineering, 2001, 17, 313 - 316.

38. M.Britchi, G.Jitianu, M.Olteanu, D.Crisan, O. Mocioiu
"Mechanical behavior of some glass ceramics used as coatings on biocompatible metals"
Proc. New research trends in Material Science,pp.266-270, 2001.

39. M. Constantinescu, C. Vuap, M.Zaharescu, M.Britchi, E.M.Anghel and M.Olteanu
"Influence of ZnO Concentration on Physico-Chemical Properties of some Oxidic Glasses that Reproduce Industrial wastes"
Progress in Molten Salt Chemistry 1, Editor R.W.Berg, H.A.Hjuler, 2000, pp179-185.

40. E.M. Anghel, E. Pavlatou, M. Balasoiu, S. Zuca,
"Phase equilibria and structure in the Na2B4O7-Na3AlF6-TiO2 system",
Advances in Molten salts, Begell House, Inc., 1999, NY-Wallingford sau High Temp. Mat. Proc. 4[3], 431-440 (2000).

41. E. M. Anghel, C. Bessada, E. Pavlatou and S. Zuca,
"Spectroscopic investigation the structure of the NaCl-Na2B4O7-Na3AlF6-TiO2 system "
Progress in Molten Salt Chemistry 1", R.W.Berg and H.A.Hjuler eds., Elsevier, 2000, p. 59-63.

42. P.M.Pavel, E.M.Anghel, M. Constantinescu and S.Serban,
"Solidification study of non-eutectic molten salt systems with acetamide and sodium acetate",
Proceeding of the 8th International Conference on Thermal Energy Storage, Stuttgart, 2000, p.321-326.

43. M.Britchi, M.Olteanu, G.Jitianu, M.Branzei, D.Gheorghe, P.Nita
"Vitroceramic coatings on metalic supports with biomedical applications"
Int,Journal of Materials and Product Technology, 15,pp 446/457, 2000.

44. A.M. Popescu, V. Constantin, R. Birjega.
"Sistemele binare NaF - LnF3 si complecsii acestora in stare topita"
Revista de Chimie, 2000, 51/6, 428-436.

45. V. Constantin, A.M. Popescu.
"Tipuri de complecsi formati in sistemele binare topite Alk - LnF3"
Revista de Chimie, 2000, 51/10, 753.

46. M. Constantinescu, G. Jitianu, C. Vuap, M. Olteanu
"Properties of some glass-ceramics in molten and solid state"
Advances in Molten Salts, "From Structural Aspects to Waste Processing", Editor Marcelle Gaune-Escard, 1999, p. 612-623.

47. M.Constantinescu, G.Jitianu, M.Britchi, C.Vuap and M.Olteanu
"Influence of composition on physico-chemical properties of some oxidic glasses that reproduce industrial wastes"
Glass Technology, 1999, 40, p. 154-9.

48. E. M. Anghel, M. Zaharescu, S. Zuca, E. Pavlatou,
"Structure and Phase Diagram of the Na2B4O7-Na3AlF6 System",
J. Mat. Sci. 34[16], 3923-3929 (1999)

49. E.M. Anghel, E.Pavlatou, R.Marchidan,
"Structural aspects of the system: Na2B4O7-Na3AlF6-TiO2, used as electrolyte in the TiB2 electrosynthesis",
British Ceram. Proc. No 60, The 6th Conf. & Exh. of the European Ceram. Soc. V.2, p.113-114 (1999).

50. M. Britchi, M. Olteanu, I. Pencea
"Optical microscopy and microhardness tests on a secondary aluminium alloy"
Int.J. of Materials and Product Technology, 1999, 14, 17-27.

51. M. Olteanu, P.M. Pavel
"Incomplete dissociation and electrical conductivity in binary molten salt mixtures with common ion".
Chem. Papers, 1999, 56(1), 6-10.

52. A.M. Popescu, V. Constantin, R. Birjega.
"Sistemele binare NaF - LnF3 si complecsii acestora in stare topita"
Revista de Chimie, 1999, 51/6, 428-436.

53. V. Constantin, A.M. Popescu.
"Tipuri de complecsi formati in sistemele binare topite Alk - LnF3"
Revista de Chimie, 1999, 51/10, 753.

54. N. Ene
"Electrosynthesis and electrochermistry of TiB2 in molten electrolyte"
Revue Roumaine de Chimie, 1999, 44/7, 643-650


Conferences abroad:

1. M.Constantinescu ,R.Piper, M.Olteanu, M.Malki, C.Bessada, P.Echegut
"Chemical stability of glasses with compositions similar to the non-volatile fraction of industrial wastes".
7th ESG Conference on Glass Science and Technology, Athens, April 25-28, 2004

2. E.M.Anghel, P.Florian, C.Bessada, D.Massiot,
"Local structure of molten and solid Na2B4O7-Na3AlF6-TiO2 mixtures: A multinuclear approach",
7th ESG Conference on Glass Science and Technology, Athens, April 25-28, 2004.

3. C.Bessada, E.M.Anghel, P.Florian, D.Massiot,
"Multinuclear NMR study of molten and solidified Na2B4O7-Na3AlF6-TiO2 mixtures",
EUCHEM Wroslaw June 23-28 2004.

4. M. Britchi, M. Olteanu, N. Ene, B. Grigoras, C. Mazilu
"Optical microscoply and microhardness characterization of some biovitroceramic coatings (composite-type) on biocompatible titanium"
The 4th Int. Conf. of Chemical Societies of the South-East European Countries, ICOSECS 4, Belgrade, 2004.

5. M. Constantinescu, M. Olteanu
"Absorption of CO2 from the atmosphere"
The 4th Int. Conf. of Chemical Societies of the South-East European Countries, Belgrade, 2004.

6. I. Galasiu, R. Galasiu, Cristina Nicolescu, G, V.aicu, J. Thonstad and G. M. Haarberg
"Iron behaviour in cryolite-alumina melts, thermodynamic consideration"
EUCHEM Wroclaw, Poland, 2004

7. I. Galasiu, R. Galasiu, Cristina Nicolescu, G, V.aicu, J. Thonstad and G. M. Haarberg
"Vanadium behaviour in cryolite-alumina melts, thermodynamic consideration"
EUCHEM Wroclaw, Poland, 2004

8. Ana Maria Popescu, Marcelle Gaune Escard, Stefania Zuca, Suzana Mihaiu, V. Constantin and S. Malyovanyi
"Tin dioxide-based inert anodes for aluminium electrolysis - variation of properties and behaviour as a function of composition and preparation"
EUCHEM Wroclaw, Poland, 2004

9. Ana Maria Popescu, V. Constantin Marcelle, Gaune Escard and M. Olteanu
"Electrochemical investigation of the fluoride complex of Ce(III) reduction in molten fluoride systems"
EUCHEM Wroclaw, Poland, 2004

10. M. Constantinescu, M.Malki, P. Echegut, C. Bessada, E.M. Anghel, I. Nuta and M. Olteanu
"Structure and properties of glasses obtained by recycling of secondary lead from acid battery plants".
X Conference on the Physics of Non-Crystalline Solids, Parma July 2003.

11. N. Ene, Cristina Donath
"Electrochemistry of K3MoCl6 in molten electrolytes"
Proceedings of the International Symposium on Ionic Liquids in Honour of Marcelle Gaune-Escard, 26-28, June 2003, Carry le Rouet, France; editors H. A. Oye and A. Jagtoyen, p. 537-547

12. I. Galasiu, Rodica Galasiu, Cristina Nicolescu, V. Istudor
"Metallic inert anodes for aluminium electrolysis"
Proceedings of the International Symposium on Ionic Liquids in Honour of Marcelle Gaune-Escard, 26-28 June 2003, Carry le Rouet, France; editors H. A. Oye and A. Jagtoyen, p. 179-182

13. I. Galasiu, Rodica Galasiu, N. Popa, Vasilica Chivu, V. Istudor, B. Borrensn
"Inert anodes for aluminium electrolysis; variation of the properties of nickel feritte ceramics as a function of the way of preparation"
Proceedings of the International Symposium on Ionic Liquids in Honour of Marcelle Gaune-Escard, 26-28, June 2003, Carry le Rouet, France; editors H. A. Oye and A. Jagtoyen, p. 183-189

14. I. Galasiu, Rodica Galasiu, G. Vlaicu,V. Istudor
"Metallic anodes for aluminium electrolysis"
Proceedings of the 12th International Symposium on Aluminium Symposium, Slovak-Norwegian Symposium on Al Smelting Technology, September 2003, Bratislava, Slovakia, p. 133-139

15. I. Galasiu, Rodica Galasiu, Cristina Nicolescu, J. Thonstad, G. H. Haarberg
"Study of behavior of the impurities with P and s in cryolite-alumina melts"
Proceedings of the 12th International Symposium on Aluminium Symposium, Slovak-Norwegian Symposium on Al Smelting Technology, September 2003, Bratislava, Slovakia, p. 140-148

16. Mariella Constantinescu, M. Malki, Rozalia Piper and M. Olteanu,
"Influence of Na2O content on the properties of glasses with compositions similar to the non-volatile fraction of industrial wastes".
EcerS, Istambul 2003.

17. C.Bessada, E.M.Anghel, P.Florian, E.Veron, D.Massiot,
High Resolution solid state NMR study and ESEM on the solidified Na3AlF6-Na2B4O7-TiO2 melts,
ECERS, Istambul, 2003

18. T.Griffiths, V.A. Volkovich, E.M.Anghel,
" Molten Salt Oxidation: A Reassessment of its Supposed Catalytic Mechanism and hence its Development for the Disposal of Waste Automotive Tires",
13th Int. Symp. On Molten Salts, Philadelphia,May, 2002.

19. M.Constantinescu, M.Malki*, I.Nuta*,P. Echegut*, C.Bessada*, E.M. Anghel and M.Olteanu.
"Preparation and properties of glasses obtained by recycling of secondary lead from acid battery plants"
Proceedings of the "Molten Salts Conference EUCHEM , Oxford, September, 2002

20. Mariana Marin, Mioara Stroe, N. Ene
"Electrode processes at Mo2B5 electrosynthesis"
NATO-ASI-Molten Salt from fundamental to Applications, Kas-Turcia, 2002, 4-14 mai

21. Mioara Stroe, Mariana Marin, N. Ene
"The anodic behavior of some Ti-based alloy"
NATO-ASI-Molten Salt from fundamental to Applications, Kas-Turcia, 2002, 4-14 mai

22. Ana Maria Popescu, Suzana Mihaiu, Stefania Zuca
"Microstructure and electrochemical behavior of some SnO2-based inert electrodes in aluminum electrolysis"
NATO-ASI-Molten Salt from fundamental to Applications, Kas-Turcia, 2002, 4-14 mai

23. V. Constantin, Ana Maria Popescu, Stefania Zuca
"Studies on the obtaining of solid metallic cerium from fluoride melts"
NATO-ASI-Molten Salt from fundamental to Applications, Kas-Turcia, 2002, 4-14 mai

24. Ana Maria Popescu
"Current efficiency obtained with SnO2-based inert anodes in laboratory aluminum cell"
NATO-ASI-Molten Salt from fundamental to Applications, Kas-Turcia, 2002, 4-14 mai

25. Suzana Mihaiu, Stefania Zuca, Ana Maria Popescu, Gh. Aldica, Maria Zaharescu
"Electrical behavior of the sintered SnO2-based ceramics"
7th European Conference of Ceramic Society, Bruges-Belgia 2002, 9-13 sept.

26. Rodica Galasiu, I. Galasiu, N. Popa, V. Chivu
"Inert anodes for aluminum electrolysis; variation of the properties of nickel ferrite ceramics as a function of the way of preparation"
Procc. 11th International Aluminum Symposium, Slovak-Norwegian Symposium on Aluminum Electrowinning, Trodheim-Bergen, sept. 2002, 19-22, pp. 133

27. I. Galasiu, Rodica Galasiu, C. Nicolescu, J. Thonstad, G.M. Haarberg
"Study of the behavior of iron and vanadium impurities in cryolite-alumina melts containing carbon dust"
Procc. 11th International Aluminum Symposium, Slovak-Norwegian Symposium on Aluminum Electrowinning, Trodheim-Bergen, sept. 2002, 19-22, pp. 209.

28. I. Nuta, C. Bessada, P. Echegut, M. Malki, F. Fayon and M. Constantinescu
"Influence de la teneur en PbO sur les proprietes physico-chimiques de verres d(oxydes modeles pour les verres de stockage"
17th Congress GERM, La Pommeraye, 2001.

29. C. Bessada, E.M. Anghel,
" Nuclear Magnetic Resonance studies of the Na2B4O7-Na3AlF6 system",
International Conference On Molten Salts Chemistry and Technology, Shanghai 8 -13 October, 2001.

30. M. Britchi, G. Jitianu, M. Olteanu, D. Crisan, A. Marcu, P. Nita
Vitroceramic oxidic systems as covering materials on titanium substrates
The 15th International Conference on Surface Modification Technologies, Indianapolis, USA, 2001.

31. M. Britchi, M. Olteanu, D. Gheorghe, M. Brハzei
Hardening of metallic surfaces by processes implying diffusion
The 15th International Conference on Surface Modification Technologies, Indianapolis, USA, 2001.

32. Mariana Marin, Mioara Stroe, N. Ene
"Electrode processes at Mo2B5 electrosynthesis"
NATO-ASI-Molten Salt from fundamental to Applications, Kas-Turcia, 2001,4-14 mai

33. Mioara Stroe, Mariana Marin, N. Ene
"The anodic behavior of some Ti-based alloy"
NATO-ASI-Molten Salt from fundamental to Applications, Kas-Turcia, 2001, 4-14 mai

34. Ana Maria Popescu, Suzana Mihaiu, Stefania Zuca
"Microstructure and electrochemical behavior of some SnO2-based inert electrodes in aluminum electrolysis"
NATO-ASI-Molten Salt from fundamental to Applications, Kas-Turcia, 2001, 4-14 mai

35. V. Constantin, Ana Maria Popescu, Stefania Zuca
"Studies on the obtaining of solid metallic cerium from fluoride melts"
NATO-ASI-Molten Salt from fundamental to Applications, Kas-Turcia, 2001, 4-14 mai

36. Ana Maria Popescu
"Current efficiency obtained with SnO2-based inert anodes in laboratory aluminum cell"
NATO-ASI-Molten Salt from fundamental to Applications, Kas-Turcia, 2001, 4-14 mai

37. Suzana Mihaiu, Stefania Zuca, Ana Maria Popescu, Gh. Aldica, Maria Zaharescu
"Electrical behavior of the sintered SnO2-based ceramics"
7th European Conference of Ceramic Society, Bruges-Belgia, 2001, 9-13 sept.

38. Rodica Galasiu, I. Galasiu, N. Popa, V. Chivu
"Inert anodes for aluminum electrolysis; variation of the properties of nickel ferrite ceramics as a function of the way of preparation"
Procc. 11th International Aluminum Symposium, Slovak-Norwegian Symposium on Aluminum Electrowinning, Trodheim-Bergen, 2001, sept. 19-22, pp. 133

39. I. Galasiu, Rodica Galasiu, C. Nicolescu, J. Thonstad, G.M. Haarberg
"Study of the behavior of iron and vanadium impurities in cryolite-alumina melts containing carbon dust"
Procc. 11th International Aluminum Symposium, Slovak-Norwegian Symposium on Aluminum Electrowinning, Trodheim-Bergen, 2001, sept. 19-22, pp. 209.

40. E.M. Anghel, C. Bessada, S. Zuca,
Spectroscopic investigation on the structure of the NaCl-Na2B4O7-Na3AlF6-TiO2",
EUCHEM 2000-Conference on Molten Salts, Karrebaeksminde, Denmark August 20-25, 2000.

41. E.M. Anghel, C. Bessada, S.Zuca, A. Meghea,
"Structural investigation as a function of composition of the NaCl-Na2B4O7-Na3AlF6-TiO2",
XXV European Congres on Molecular Spectroscopy, Coimbra-Portugal, 27 August-1 September 2000.

42. M. Britchi, M. Olteanu, G. Jitianu, M. Brハzei, D. Gheorghe, P. Nita
"Vitroceramic coatings on metallic supports with biomedical applications"
The 14th International Conference on Surface Modification Technology, Paris, Franta, 2000

43. M. Britchi, M. Olteanu, M. Brハzei, D. Gheorghe
"Hardening of copper surface by beryllium diffusion"
Materials Week 2000, International Congress on Advanced Materials, Processes and Technologies, Muenchen

44. M. Constantinescu, C. Vuap, M. Zaharescu, M. Britchi, E. M. Anghel, M. Olteanu
"Influence of ZnO content on physico - chemical properties of some oxidic glasses that reproduce industrial Wastes"
EUCHEM Conference on Molten Salts, Karrenbaeksminde, Danemarca, 2000.

Conferences in Romania:

1. E.M. Anghel, C. Bessada, P.Florian, D.Massiot,
"High Resolution solid state NMR study on the solidified Na3AlF6-Na2B4O7-TiO2 melts",
The 11th Physical Chemistry Conference", September 2003, Timisoara, Romania.

2. M. Olteanu, M.Malki, P. Echegut, C. Bessada, E.M. Anghel, I. Nuta, I.Toma and M. Constantinescu
"Characterization of a glass obtained by recycling of secondary lead from acid battery plant".
The 11th Physical Chemistry Conference", September 2003, Timisoara, Romania.

3. C. Bessada, M. Malki, M. Constantinescu, P. Echegut, I. Nuta and M. Olteanu,
"Structural aspects and properties of some oxide glasses with a quaternary matrix SiO2-Al2O3-Na2O-CaO-PbO"
The 11th Physical Chemistry Conference", September 2003, Timisoara, Romania.

4. P. M. Pavel, and M. Constantinescu,
"Study of crystallization kinetics in glass-forming liquids. Theory"
The 11th Physical Chemistry Conference", September 2003, Timisoara.

5. M. Malki. , M. Constantinescu, R. Piper, C. Vuap and M. Olteanu,
"Chemical stability of glasses with compositions similar to the non-volatile fraction of industrial wastes"
The 11th Physical Chemistry Conference", September 2003, Timisoara.

6. M.Britchi, M.Olteanu, N.Ene,B.Grigoras, C.Mazilu
"Evolution of fracture toughness and brittleness from Vickers hardness measurements on biovitroceramic coatings"
The 11th Physical Chemistry Conference", September 2003, Timisoara.

7. M.Britchi, M. Olteanu, G. Jitianu, D. Gheorghe, M. Branzei
Composite biovitrocreamic materials as coating layers on biocompatible metallic supports
MATEHM'02, The 3rd Int. Conf. on Materials and Manufacturing Technologies, Cluj-Napoca, Romania, 2002.

8. N. Ene, Cristina Donath, Elena Ciurla
"Electrochemistry of Mo3+ in molten salts"
The 11th Physical Chemistry Conference with International Participation ROMPHYSCHEM 11, 2-5 September, 2003, Timisoara, Romania

9. N. Ene, Cristina Donath, Elena Ciurla
"Electrochemical synthesis of Mo2B5 from molten alkali halide electrolytes"
A treia Conferina Nationala directii Noi de Cercetare in Stiinta Materialelor-ARM, 12-13 septembrie, 2003, Constanta, Romania

10. N. Ene, Elena Ciurla, Cristina Donath
"The corrosion of some titanium alloys in molten electrolytes"
A treia Conferina Nationala directii Noi de Cercetare in Stiinta Materialelor-ARM, 12-13 septembrie, 2003, Constanta, Romania

11. M. Britchi, M. Olteanu, D. Gheorghe, M. Brハzei
Mechanical behaviour of composite biovitroceramic-metal couple. Influence of Ti powder additions
The 3rd Int. Conf. of Chem. Soc. of the South-Eastern European Countries on Chemistry, Bucharest, Romania,2002.

12. Cristina Donath, N. Ene
"Electroreduction of Nb ions in the molten alkali halide"
Second European Conference and Exhibition on Advanced Materials and Technology, 2002, 9-13 sept. Bucharest, pp. 61-62

13. Cristina Donath, N. Ene
"Studies of Niobium electrtochemistry in KCl-NaF-LiF molten electrolytes"
Procc. 2nd International Symposium on Electrochemistry- A Frontier Field of Theoretical and Practical Interest, sept. 2002, 13-15, Bucharest, CD-09

14. Cristina Donath, N. Ene
"Contribution to chemistry and electrochemistry of Nb ions in molten electrolytes"
The 2nd National Conference "New Research trends in Material Science" Constanta, 2002, 24- 26 sept. pp. 67-69

15. Suzana Mihaiu, Gh. Aldica, Ana Maria Popescu, O. Scarlat, Maria Zaharescu
"SnO2-based ceramics with electronic type conduction"
Conferinta Jubiliara a Societatii de Ceramica, 22 iunie, Bucuresti, 2002, pp. 61-62

16. M. Britchi, G. Jitianu, M. Olteanu, D. Crisan, O. Mocioiu
"Mechanical behaviour of some glass - ceramics used as coatings on biocompatible materials"
The 2nd Conference "New Research Trends in Material Science ARM - 2", Constanta, 2001

17. M. Britchi, M.Codescu, W.Kappel, P. Miron
"Influence of granulometric distribution of Nd-Fe-B alloys for high energy permanent magnets"
The 2nd Conference "New Research Trends in Material Science ARM - 2", Constanta, 2001

18. M. Constantinescu, G.Jitianu, E.M. Anghel, C. Vuap, A. Meghea, I.Nuta and M. Olteanu
"Influence of Heavy Metal Oxides on Structure and Properties of some Vitrified Synthetic Residue"
The 10th Conference on Physical Chemistry, 26-29 September, 2000, Iasi, Romania.

19. M. Olteanu, M. Constantinescu, M. Zaharescu, I. Nuta, O. Mocioiu, M. Britchi
"Industrial residue inertization by vitrification"
The 3rd International Conference of Balkan Environmental Association on Transboundary Pollution, Bucuresti, 2000.

20. M. Constantinescu, M. Olteanu, I. Nuta, O. Mocioiu, M. Britchi, M. Zaharescu
Inertization of some industrial wastes with high PbO content
VIII th Glass Symposium on Achievements and Trends in Glass Industry, Alba Iulia, Romania, 2000.

21. M. Constantinescu, M. Olteanu, I. Nuta, M. Zaharescu
"Industrial residue inertization by vitrification"
The 10th Conference on Physical Chemistry, 26-29 September, Iasi, 2000.

22. M.Britchi, G.Jitianu, M.Olteanu, D.Crisan, P.Nita
"Physico-chemical characterization of vitroceramic-metal systems with applications in implantology"
The 10th Conference on Physical Chemistry, 26-29 September, 2000, Iasi.

23. M. Maria, M. Stroe, N. Ene.
"Electrochimia si electrosinteza Mo2B5 in saruri topite"
The 10th Conference on Physical Chemistry, Sept. 26-29, 2000, Iasi, Romania

Fellowships:

1. European Fellowship "Access to Research Infrastructures-Improving Human Potential Program"
HPRI-CT-1999-00042, at Centre de Recherche sur les Materiaux a Haute Temperatures-CNRS, Orleans, France (E.M.Anghel 15-28 0ct.2000)
Topic: High-Temperature and MAS NMR measurements.

2. European Fellowship "Access to Research Infrastructures-Improving Human Potential Program"
HPRI-CT- 1999-00042, at Centre de Recherche sur les Materiaux a Haute Temperatures-CNRS, Orleans, France
Title: "High Temperature and MAS NMR investigation of the ternary and quaternary mixture of the NaCl- Na2B4O7-Na3AlF6-TiO2 system".
E.M. Anghel ( November 4-17, 2001)

3. Royal Society Fellowship at University of Leeds Waste (medical disposal and tire scrap) destruction in molten carbonates
E.M. Anghel 217th June 2001-17th January 2002

4. CNRS-Romanian Academy cooperation:
"Etude structurale d'electrolytes utilisis en synthese electrochimique"
la Centre de Recherche sur les Materiaux a Haute Temperatures-CNRS, Orleans,
France, E.M. Anghel 18th November-2nd December 2001

5. Fifth Post-Graduate Summer School on Green Chemistry European Comision-TMR Programme,
Venezia, Italy, E.M. Anghel, September 8-14, 2002

6. European Felloship "Acces to Research Infrastructures-Improving Human Potential Program"
HPRI-CT-1999-00042, ala Centre de Recherche sur les Materiaux a Haute Temperatures-CNRS, Orleans, France,
Title: "High Resolution MAS NMR study of the Na2B4O7-Na3AlF6-TiO2 system" E.M.Anghel, September 15-22, 2002

7. CNRS-Romanian Academy cooperation: "Etude structurale d'electrolytes utilisis en synthese electrochimique"
at Centre de Recherche sur les Materiaux a Haute Temperatures-CNRS, Orleans, France,
E.M. Anghel, 23rd September-6th October 2002

8. CNRS-Romanian Academy cooperation:
"Etude structurale d'electrolytes utilisis en synthese electrochimique"
at Centre de Recherche sur les Materiaux a Haute Temperatures-CNRS, Orleans, France,
E.M. Anghel, September 15-30, 2003.

9. CNRS-Romanian Academy cooperation:
"Etude du systeme NaCl-Na2B4O7-Na3AlF6-TiO2 par RMN haute resolution solide et haute temperature"
at Centre de Recherche sur les Materiaux a Haute Temperatures- CNRS, France,
E.M. Anghel 27th June-11th July 2004.

10. EEC facility, CRMHT - CNRS Orleans, France
"Access to Research Infrastructures-Improving Human Potential Program"
HPRI-CT-1999-00042, , Orleans, France
Title: "High temperature and MAS NMR investigation of the synthetic glass-ceramics similar to those obtained by industrial waste vitrification"
M. Constantinescu 16 June-2 July 2001

11. EEC facility, CRMHT - CNRS Orleans, France
"Acces to Research Infrastructures-Improving Human Potential Program"
HPRI-CT-1999-00042, , Orleans, France
Title: "High temperature and MAS NMR investigation of the synthetic glass-ceramics similar to those obtained by industrial waste vitrification"
M.Constantinescu 1-8 11 2002

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